25 research outputs found
Enhanced Raman and photoluminescence response in monolayer MoS due to laser healing of defects
Bound quasiparticles, negatively charged trions and neutral excitons, are
associated with the direct optical transitions at the K-points of the Brillouin
zone for monolayer MoS. The change in the carrier concentration,
surrounding dielectric constant and defect concentration can modulate the
photoluminescence and Raman spectra. Here we show that exposing the monolayer
MoS in air to a modest laser intensity for a brief period of time enhances
simultaneously the photoluminescence (PL) intensity associated with both trions
and excitons, together with 3 to 5 times increase of the Raman intensity
of first and second order modes. The simultaneous increase of PL from trions
and excitons cannot be understood based only on known-scenario of depletion of
electron concentration in MoS by adsorption of O and HO molecules.
This is explained by laser induced healing of defect states resulting in
reduction of non-radiative Auger processes. This laser healing is corroborated
by an observed increase of intensity of both the first order and second order
2LA(M) Raman modes by a factor of 3 to 5. The A mode hardens by
1.4 cm whereas the E mode softens by 1 cm.
The second order 2LA(M) Raman mode at 440 cm shows an increase in
wavenumber by 8 cm with laser exposure. These changes are a
combined effect of change in electron concentrations and oxygen-induced lattice
displacements.Comment: 15 pages, 5 figures, Journal of Raman Spectroscopy, 201
Symmetry-dependent phonon renormalization in monolayer MoS2 transistor
Strong electron-phonon interaction which limits electronic mobility of
semiconductors can also have significant effects on phonon frequencies. The
latter is the key to the use of Raman spectroscopy for nondestructive
characterization of doping in graphene-based devices. Using in-situ Raman
scattering from single layer MoS electrochemically top-gated field effect
transistor (FET), we show softening and broadening of A phonon with
electron doping whereas the other Raman active E mode remains
essentially inert. Confirming these results with first-principles density
functional theory based calculations, we use group theoretical arguments to
explain why A mode specifically exhibits a strong sensitivity to
electron doping. Our work opens up the use of Raman spectroscopy in probing the
level of doping in single layer MoS-based FETs, which have a high on-off
ratio and are of enormous technological significance.Comment: 5 pages, 3 figure
Sharp Raman Anomalies and Broken Adiabaticity at a Pressure Induced Transition from Band to Topological Insulator in Sb2Se3
The nontrivial electronic topology of a topological insulator is thus far
known to display signatures in a robust metallic state at the surface. Here, we
establish vibrational anomalies in Raman spectra of the bulk that signify
changes in electronic topology: an E2 g phonon softens unusually and its
linewidth exhibits an asymmetric peak at the pressure induced electronic
topological transition (ETT) in Sb2Se3 crystal. Our first-principles
calculations confirm the electronic transition from band to topological
insulating state with reversal of parity of electronic bands passing through a
metallic state at the ETT, but do not capture the phonon anomalies which
involve breakdown of adiabatic approximation due to strongly coupled dynamics
of phonons and electrons. Treating this within a four-band model of topological
insulators, we elucidate how nonadiabatic renormalization of phonons
constitutes readily measurable bulk signatures of an ETT, which will facilitate
efforts to develop topological insulators by modifying a band insulator
Coupled Phonons, Magnetic Excitations and Ferroelectricity in AlFeO3: Raman and First-principles Studies
We determine the nature of coupled phonons and magnetic excitations in AlFeO3
using inelastic light scattering from 5 K to 315 K covering a spectral range
from 100-2200 cm-1 and complementary first-principles density functional
theory-based calculations. A strong spin-phonon coupling and magnetic ordering
induced phonon renormalization are evident in (a) anomalous temperature
dependence of many modes with frequencies below 850 cm-1, particularly near the
magnetic transition temperature Tc ~ 250 K, (b) distinct changes in band
positions of high frequency Raman bands between 1100-1800 cm-1, in particular a
broad mode near 1250 cm-1 appears only below Tc attributed to the two-magnon
Raman scattering. We also observe weak anomalies in the mode frequencies at ~
100 K, due to a magnetically driven ferroelectric phase transition.
Understanding of these experimental observations has been possible on the basis
of first-principles calculations of phonons spectrum and their coupling with
spins
Raman Evidence for Superconducting Gap and Spin-Phonon Coupling in Superconductor Ca(Fe0.95Co0.05)2As2
Inelastic light scattering studies on single crystal of electron-doped
Ca(Fe0.95Co0.05)2As2 superconductor, covering the tetragonal to orthorhombic
structural transition as well as magnetic transition at TSM ~ 140 K and
superconducting transition temperature Tc ~ 23 K, reveal evidence for
superconductivity-induced phonon renormalization; in particular the phonon mode
near 260 cm-1 shows hardening below Tc, signaling its coupling with the
superconducting gap. All the three Raman active phonon modes show anomalous
temperature dependence between room temperature and Tc i.e phonon frequency
decreases with lowering temperature. Further, frequency of one of the modes
shows a sudden change in temperature dependence at TSM. Using first-principles
density functional theory-based calculations, we show that the low temperature
phase (Tc < T < TSM) exhibits short-ranged stripe anti-ferromagnetic ordering,
and estimate the spin-phonon couplings that are responsible for these phonon
anomalies
Etude de filtration sur charbon actif regenere biologiquement. Procede C.E.A
SIGLECNRS-CDST / INIST-CNRS - Institut de l'Information Scientifique et TechniqueFRFranc
Raman signatures of pressure induced electronic topological and structural transitions in Bi2Te3
We report Raman signatures of electronic topological transition (ETT) at 3.6 GPa and rhombohedral (alpha-Bi2Te3) to monoclinic (beta-Bi2Te3) structural transition at similar to 8 GPa. At the onset of ETT, a new Raman mode appears near 107 cm(-1) which is dispersionless with pressure. The structural transition at similar to 8 GPa is marked by a change in pressure derivative of A(1g) and E-g mode frequencies as well as by appearance of new modes near 115 cm(-1) and 135 cm(-1). The mode Grilneisen parameters are determined in both the alpha and beta-phases. (C) 2011 Elsevier Ltd. All rights reserved
Photophysical behavior of poly(propyl ether imine) dendrimer in the presence of nitroaromatic compounds
This paper deals with a study of the photophysical property of poly(ether imine) (PETIM) dendritic macromolecule in the presence of aromatic compounds. The inherent photoluminescence property of the dendrimer undergoes quenching in the presence of guest aromatic nitro-compounds. From life-time measurements study, it is inferred that the lifetimes of luminescent species of the dendrimer are not affected with nitrophenols as guest molecules, whereas nitrobenzenes show a marginal change in the lifetimes of the species. Raman spectral characteristic of the macromolecular host-guest complex is conducted in order to identify conformational change of the dendrimer and a significant change in the stretching frequencies of methylene moieties of the dendrimer is observed for the complex with 1,3,5-trinitrobenzene, when compared to other complexes, free host and guest molecules. The photophysical behavior of electron-rich, aliphatic, neutral dendritic macromolecule in the presence of electron-deficient aromatic molecules is illustrated in the present study. (C) 2012 Elsevier B.V. All rights reserved